If your Product Advertising API calls return TooManyRequests, you're being throttled. It's the most common PA API problem, especially for newer affiliates — and it's mostly by design.
Every account starts with one request per second and 8,640 requests per day. From there, your limit scales with the shipped-item revenue your affiliate links drive: roughly one extra request per day for every five cents of revenue over the last 30 days. Drive no sales, and your quota stays at the floor — or drops back to it. Amazon documents this in their API rates guide.
Tools that check your keys often fire several requests in a burst (one per Amazon locale you've configured). A burst can trip the per-second limit even when your steady usage is fine — so a settings page can show throttling errors while normal searches still work.
New keys on the same associate account inherit the same limits, and retry storms make bursts worse. Don't bother.
Try Table Labs — $20/month, unlimited tables